Enhanced solubilization of ketoprofen using Triton X-100, Triton X-165, Brij C10, and their mixed micelle systems

Ketoprofen, a Biopharmaceutics Classification System (BCS) class II drug, exhibits poor aqueous solubility, which limits its bioavailability and therapeutic performance. To address this, we investigated micellar systems composed of Triton X-100, Triton X-165, and Brij C10, studied individually and i...

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Elmentve itt :
Bibliográfiai részletek
Szerzők: Farkaš Agatić Zita
Lalić-Popović Mladena
Todorović Nemanja
Stjepanović Ana
Tepavčević Vesna
Bećarević Mirjana
Poša Mihalj
Testületi szerző: 31th International Symposium on Analytical and Environmental Problems
Dokumentumtípus: Könyv része
Megjelent: University of Szeged Szeged 2025
Sorozat:Proceedings of the International Symposium on Analytical and Environmental Problems 31
Kulcsszavak:Gyógyszerkémia, Fizikai kémia, Kolloidkémia, Gyógyszertechnológia
Tárgyszavak:
Online Access:http://acta.bibl.u-szeged.hu/88621
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040 |a SZTE Egyetemi Kiadványok Repozitórium  |b hun 
041 |a eng 
100 2 |a Farkaš Agatić Zita 
245 1 0 |a Enhanced solubilization of ketoprofen using Triton X-100, Triton X-165, Brij C10, and their mixed micelle systems  |h [elektronikus dokumentum] /  |c  Farkaš Agatić Zita 
260 |a University of Szeged  |b Szeged  |c 2025 
300 |a 61-63 
490 0 |a Proceedings of the International Symposium on Analytical and Environmental Problems  |v 31 
520 3 |a Ketoprofen, a Biopharmaceutics Classification System (BCS) class II drug, exhibits poor aqueous solubility, which limits its bioavailability and therapeutic performance. To address this, we investigated micellar systems composed of Triton X-100, Triton X-165, and Brij C10, studied individually and in binary and ternary mixtures, with the aim of enhancing solubilization efficiency. Critical micelle concentrations (cmc) were determined by fluorescence spectroscopy using pyrene as a probe, and the thermodynamics of mixed micelle formation were evaluated by Rubingh’s model, Regular Solution Theory, and the Margules function to obtain interaction parameters and excess Gibbs free energies. Solubilization of ketoprofen was quantified by HPLC in terms of molar solubilization ratios and partition coefficients. Brij C10 exhibited the lowest cmc and the highest solubilization capacity, with molar solubilization ratios exceeding 6, while Triton micelles showed lower efficiency. Binary Brij–Triton mixtures revealed synergistic stabilization but occasional antagonistic solubilization, highlighting a trade-off between stability and drug incorporation. The ternary system, although thermodynamically stable, showed reduced solubilization due to compact packing. Overall, Brij-rich systems proved to be the most effective carriers, combining low cmc with high solubilization efficiency. These findings provide a thermodynamic basis for the rational design of surfactant mixtures for the solubilization of poorly water-soluble drugs. 
650 4 |a Természettudományok 
650 4 |a Kémiai tudományok 
650 4 |a Orvos- és egészségtudomány 
650 4 |a Általános orvostudomány 
695 |a Gyógyszerkémia, Fizikai kémia, Kolloidkémia, Gyógyszertechnológia 
700 0 2 |a Lalić-Popović Mladena  |e aut 
700 0 2 |a Todorović Nemanja  |e aut 
700 0 2 |a Stjepanović Ana  |e aut 
700 0 2 |a Tepavčević Vesna  |e aut 
700 0 2 |a Bećarević Mirjana  |e aut 
700 0 2 |a Poša Mihalj  |e aut 
711 |a 31th International Symposium on Analytical and Environmental Problems  |c Szeged  |d 2025. október 13-14. 
856 4 0 |u http://acta.bibl.u-szeged.hu/88621/1/proceedings_of_isaep_2025_061-063.pdf  |z Dokumentum-elérés